| Ultra spherical granulation of thermoplastics and compounds by a vibrational dropping process |
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Thorsten Brandau and Egbert Brandau
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Introduction
Trends in plastic development and processing have
recently been moving toward increasingly high quality and free
flowing particles. The well approved industrial processes do not
always meet the exacting standards which modern manufacturing
demands of them due to their varying size distribution and odd
shapes. These properties are detrimental to efficient
processing and lead to agglomeration, inexact dosage, abrading
with loss of material or low reproducibility of castings. The
use of small and perfectly round microspheres with exactly the
same size circumvents all of the disadvantages that are
encountered while using powders and granulates.
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Production process
The
recent development describes a method for producing plastic
particles with tailored properties and with a uniform spherical
geometry and a narrow grain size distribution. The liquid
plastic is gently pumped through a vibrating nozzle system where
upon exiting the fluid stream breaks up into uniform droplets. The
surface tension of these droplets molds them into perfect spheres
in which solidification is induced during a short period of free
fall. Solidification can be induced in a gaseous medium through
cooling or drying and/or in a liquid medium through cooling or
chemical reaction. Amplitude and frequency of the nozzle
oscillation or the liquid oscillation are held constant to attain
a monodisperse grain size distribution. To ensure that the
droplets are not flattened on entry into the cooling liquid, i.e.
undergo a geometric change, it is provided that the droplets enter
at an accurate angle or tangential a liquid layer having one
laminar flow proportion. The flow direction should be the same as
the fall direction of the droplets in ball form. The cooling
liquid has a temperature that is in the range of the Vicat
temperature of the plastic droplets.
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It is possible to dispose
a mushroom-shaped liquid distribution unit underneath the nozzle
head, along the surface of which a liquid layer is formed. The
mushroom-like arrangement has a diameter such that the droplets
enter the liquid layer in the substantially vertical area thereof.
An appropriate liquid layer can also be obtained by a funnel-like
arrangement with a convex design of the wall faces in relation to
the drop distance. Vibration
can be induced via an elastic membrane directly to the small
quantity of liquid plastic just before exiting the nozzles. This
has the big advantage that only small vibrators are able to
vibrate the laminar fluid stream. The operation of a nozzle system
of about 300 nozzles needs a magnetic vibrator with a sine force
of 20N. If the nozzle plate has to be vibrated itself it can be
fabricated out of Titanium to avoid very heavy permanent magnet
vibrators. For high temperature operation and corrosive materials
special materials like ceramics or graphite can be used as nozzle
plate material.
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Types of Production Facilities
Microsphere
production units can be designed and constructed from the
laboratory scale up to full size production plants. The
throughput and the price of the production units vary with the
size of the microspheres and the complexity involved in the
solidification process. Based on a sphere diameter of 1 mm lab
installations have a plastic throughput of about 20 kg/h, pilot
plants about 100 to 200 kg/h, and production units can be
installed up to 2 t/h. Microsphere production units have a
minimal space requirement (15 to 40 sq. Feet), the energy
consumption is very low and they are noiseless during operation.
These units operate at atmospheric pressure or slightly above and
can be designed to be explosion proof according to the GLP/GMP
guide lines. Microsphere production units need practically no
maintenance, therefore only a minimal staff is required. Units
with fully automated controls and remote monitoring can be
delivered as an option.
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Applications and Types of Microspheres
Microspheres
produced from molten organics and polymers can be used for dosing,
proportioning, compounding, coloring and light stabilization.
Microspheres with dissolved or embedded active agents, with or
without coating or coloring are used for numerous plastic,
pharmaceutical and cosmetic products. Plastic materials like
polyethylene, polypropylene, polymethacrylates, polyesters, i.e.
most of the thermoplastics and the non curing components of
thermosetting like novolak and epoxy resins can be granulated to
microspheres. Using special mixtures of organic and aqueous
solutions polyamides, polystyrene and others or compounds can be
transferred to spheres. Microspheres produced by this unique
process in the rang of 100 µm and 5000 µm have a
monodisperse grain size distribution, are free flowing and roll
with practically no friction that means there is no abrasion
guaranteeing a dust free environment.
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Aktualisiert Montag, 29. Dezember 2008 |
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